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101.
Xiaoyang Du Yi Yuan Lei Zhou Hui Lin Caijun Zheng Junyi Luo Zhenhua Chen Silu Tao Liang‐Sheng Liao 《Advanced functional materials》2020,30(15)
Charge transfer state (CT) plays an important role in exciton diffusion, dissociation, and charge recombination mechanisms. Enhancing the utilization and suppressing the recombination process of CT excitons is a promising way to improve the performance of organic solar cells (OSCs). Here, an effective method is presented via introducing a delayed fluorescence (DF) emitter 3,4‐bis(4‐(diphenylamino)phenyl)acenaphtho[1,2‐b]pyrazine‐8,9‐dicarbonitrile (APDC‐TPDA) in OSCs. The long‐lifetime singlet excitons on APDC‐TPDA can transfer to polymer donors to prolong exciton lifetime, which ensures sufficient time for diffusion and dissociation. Concurrently, the high triplet energy level (T1) of the DF material can also prevent the reverse energy transfer from CT to T1. APDC‐TPDA‐containing ternary OSCs shows a high PCE of 16.96% with a reduced recombination energy loss of 0.46 eV. It is noteworthy that the ternary OSC also exhibits superior storage stability. After 55 days of storage, the PCE of the ternary OSC still retains about 96% of its primitive state. Furthermore, this ternary strategy is efficient and universally applicable to OSCs, and positive results can be obtained in different systems with different DF emitters. These results indicate that the ternary strategy provides a new design idea to realize high performance OSCs. 相似文献
102.
Ning An Yunhao Cai Hongbo Wu Ailing Tang Kangning Zhang Xiaotao Hao Zaifei Ma Qiang Guo Hwa Sook Ryu Han Young Woo Yanming Sun Erjun Zhou 《Advanced materials (Deerfield Beach, Fla.)》2020,32(39):2002122
Compared with inorganic or perovskite solar cells, the relatively large non-radiative recombination voltage losses (ΔVnon-rad) in organic solar cells (OSCs) limit the improvement of the open-circuit voltage (Voc). Herein, OSCs are fabricated by adopting two pairs of D–π–A polymers (PBT1-C/PBT1-C-2Cl and PBDB-T/PBDB-T-2Cl) as electron donors and a wide-bandgap molecule BTA3 as the electron acceptor. In these blends, a charge-transfer state energy (ECT) as high as 1.70–1.76 eV is achieved, leading to small energetic differences between the singlet excited states and charge-transfer states (ΔECT ≈ 0.1 eV). In addition, after introducing chlorine atoms into the π-bridge or the side chain of benzodithiophene (BDT) unit, electroluminescence external quantum efficiencies as high as 1.9 × 10−3 and 1.0 × 10−3 are realized in OSCs based on PBTI-C-2Cl and PBDB-T-2Cl, respectively. Their corresponding ΔVnon-rad are 0.16 and 0.17 V, which are lower than those of OSCs based on the analog polymers without a chlorine atom (0.21 and 0.24 V for PBT1-C and PBDB-T, respectively), resulting in high Voc of 1.3 V. The ΔVnon-rad of 0.16 V and Voc of 1.3 V achieved in PBT1-C-2Cl:BTA3 OSCs are thought to represent the best values for solution-processed OSCs reported in the literature so far. 相似文献
103.
104.
Weikang Dong Ruishi Qi Tiansheng Liu Yi Li Ning Li Ze Hua Zirui Gao Shuyuan Zhang Kaihui Liu Jiandong Guo Peng Gao 《Advanced materials (Deerfield Beach, Fla.)》2020,32(46):2002014
Hyperbolic phonon polaritons (HPhPs) in orthorhombic-phase molybdenum trioxide (α-MoO3) show in-plane hyperbolicity, great wavelength compression, and ultralong lifetime, therefore holding great potential in nanophotonic applications. However, its polaritonic response in the far-infrared (FIR) range remains unexplored due to challenges in experimental characterization. Here, monochromated electron energy loss spectroscopy (EELS) in a scanning transmission electron microscope (STEM) is used to probe HPhPs in α-MoO3 in both mid-infrared (MIR) and FIR frequencies and correlate their behaviors with microstructures and orientations. It is found that low structural symmetry leads to various phonon modes and multiple Reststrahlen bands (RBs) over a broad spectral range (over 70 meV) and in different directions (55–63 meV and 119–125 meV along the b-axis, 68–106 meV along the c-axis, and 101–121 meV along the a-axis). These HPhPs can be selectively excited by controlling the direction of swift electrons. These findings provide new opportunities in nanophotonic and optoelectronic applications, such as directed light propagation, hyperlenses, and heat transfer. 相似文献
105.
During the last few decades, photothermal radiometry (PTR) has been greatly developed and widely applied in the field of nondestructive testing. However, the traditional PTR system employs an expensive lock-in amplifier to detect the weak photothermal signal, which leads to high cost and long test time. In this paper, a fast transmission PTR system based on sampling by using an internal computer sound card was developed to lower the system cost and shorter the test time. A piece of amorphous silicon (a:Si) thin film solar cells with artificial defects was prepared and tested by the system. The results show that the sharpened defects can be identified easily and quickly according to the significant peaks of the original infrared signal sampled by the internal computer sound card. Furthermore, more detailed defects can be investigated by processing the infrared signal. These validate the effectiveness of the proposed transmission PTR system as a low cost and efficient non-destructive test technique. 相似文献
106.
107.
动力头是旋挖钻机的关键部件,其性能好坏直接影响钻机整机性能的。文中介绍了TR 180旋挖钻机动力头的结构设计,着重分析了齿轮箱传动系统、滑动支架总成和缓冲装置。 相似文献
108.
《Intermetallics》2015
An equiatomic CoCrFeNiMn high-entropy alloy was synthesized by mechanical alloying (MA) and spark plasma sintering (SPS). During MA, a solid solution with refined microstructure of 10 nm which consists of a FCC phase and a BCC phase was formed. After SPS consolidation, only one FCC phase can be detected in the HEA bulks. The as-sintered bulks exhibit high compressive strength of 1987 MPa. An interesting magnetic transition associated with the structure coarsening and phase transformation was observed during SPS process. 相似文献
109.
This paper presents a fast distance relay for series compensated transmission lines based on the R–L differential-equation algorithm using the theory of equal transfer process of transmission lines. The measuring distances based on the proposed algorithm can fast approach the actual value of fault distance when a fault occurs in front of the series capacitor. When a fault occurs behind of the series capacitor, the fault loop, including the series capacitor, does not match the R–L transmission line model, so the measuring distances fluctuate severely. Based on this, the relative position of the fault with respect to the series capacitor can be judged effectively according to the fluctuation range of the measuring distances, and the accurate fault location can be obtained fast. A variety of PSCAD/EMTDC simulation tests show that the new relay has fast operating speed and high accuracy when applied to the long series compensated transmission lines. 相似文献
110.
以昆明—曼谷国际公路k70路堤加固工程为背景,采用原位测试方法,完成了不同工况下预应力锚索桩板墙承载特性的现场试验。通过观测结构位移、土压力、桩身内力以及锚索预应力等,系统分析了预应力锚索桩板墙的受力特性与力学行为。锚索桩板墙对高路堤的加固效果显著,填筑初期结构位移随填土高度线性增加,锚索施工后增速有所减缓;初始填筑阶段,抗滑桩变形以刚性倾斜为主,随着锚索张拉和桩后填土不断增高桩身产生了较为明显的弯曲变形。作用在抗滑桩后的土压力大致呈三角形分布,板后土压力大致呈抛物线型分布;相同埋深条件下作用在抗滑桩上的土压力明显大于挡板,原因在于相邻抗滑桩间产生了明显的土拱效应,下部相邻抗滑桩间的土拱效应更强;与解析解的对比结果表明,实测最大桩后土压力与滑坡推力接近,远小于被动土压力;实测板后土压力与主动土压力接近,工程设计中可选取Rankine主动土压力作为挡板的设计荷载,在不利位置采取增大板厚等措施避免挡板发生破坏。采用弹性弯曲梁理论对锚索桩板墙内力计算的结果与实测结果基本一致。张拉锁定初期锚索预应力损失较大,约为设计荷载的10%,后期锚索预应力逐渐趋于稳定,锚索预应力长期损失约为设计荷载值的12%~15%。 相似文献